Furolabdane diterpenoids from Pseudodictamnus aucheri (Boiss.) Salmaki & Siadati (Lamiaceae) as chemophenetic markers
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Furolabdane diterpenoids from Pseudodictamnus aucheri (Boiss.) Salmaki & Siadati (Lamiaceae) as chemophenetic markers. / Sadani, Sanaz; Sarrafi, Yaghoub; Stærk, Dan.
I: Biochemical Systematics and Ecology, Bind 98, 104304, 2021.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Furolabdane diterpenoids from Pseudodictamnus aucheri (Boiss.) Salmaki & Siadati (Lamiaceae) as chemophenetic markers
AU - Sadani, Sanaz
AU - Sarrafi, Yaghoub
AU - Stærk, Dan
PY - 2021
Y1 - 2021
N2 - In the present study, the chemical constituents of the aerial parts of Pseudodictamnus aucheri (Boiss.) Salmaki & Siadati (formerly Ballota aucheri (Boiss.)), which is endemic to Iran, are reported. Six furolabdane-type diterpenoids, i.e., ballotenol, ballotinone, ballonigrin, 6β,9α-dihydroxy-15,16-epoxylabda-13(16),14-dien-7-one, hispanolone,and leoheterin (7β,9α-dihydroxy-15,16-poxylabda-13(16),14 dien-6 one), and the flavonoid ladanein were isolated from the chloroform extract of P. aucheri and identified using high-performance liquid chromatography-photodiode-array detection-high-resolution mass spectrometry and nuclear magnetic resonance spectroscopy. Ballotenol, 6β,9α-dihydroxy-15,16-epoxylabda-13(16),14-dien-7-one, hispanolone, and ladanein were identified from P. aucheri for the first time, and 6β,9α-dihydroxy-15,16-epoxylabda-13(16),14-dien-7-one, hispanolone, and leoheterin, were identified as chemophenetic markers to support a new circumscription of Ballota and Pseudodictamnus within tribe Marrubieae.
AB - In the present study, the chemical constituents of the aerial parts of Pseudodictamnus aucheri (Boiss.) Salmaki & Siadati (formerly Ballota aucheri (Boiss.)), which is endemic to Iran, are reported. Six furolabdane-type diterpenoids, i.e., ballotenol, ballotinone, ballonigrin, 6β,9α-dihydroxy-15,16-epoxylabda-13(16),14-dien-7-one, hispanolone,and leoheterin (7β,9α-dihydroxy-15,16-poxylabda-13(16),14 dien-6 one), and the flavonoid ladanein were isolated from the chloroform extract of P. aucheri and identified using high-performance liquid chromatography-photodiode-array detection-high-resolution mass spectrometry and nuclear magnetic resonance spectroscopy. Ballotenol, 6β,9α-dihydroxy-15,16-epoxylabda-13(16),14-dien-7-one, hispanolone, and ladanein were identified from P. aucheri for the first time, and 6β,9α-dihydroxy-15,16-epoxylabda-13(16),14-dien-7-one, hispanolone, and leoheterin, were identified as chemophenetic markers to support a new circumscription of Ballota and Pseudodictamnus within tribe Marrubieae.
U2 - 10.1016/j.bse.2021.104304
DO - 10.1016/j.bse.2021.104304
M3 - Journal article
VL - 98
JO - Biochemical Systematics and Ecology
JF - Biochemical Systematics and Ecology
SN - 0305-1978
M1 - 104304
ER -
ID: 273717908